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on September 20, 2023

Unlocking the Enigma: Decoding the Four-Digit Number Mystery of Apatite’s Crystal Cleavage

Geology & Landform

Apatite’s Crystal Cleavage: Cracking the Code of Those Weird Four-Digit Numbers

Apatite. The name itself hints at deception, coming from the Greek word “apatein,” meaning “to deceive.” And it’s true – this mineral group is a master of disguise, often fooling people into thinking it’s something else entirely! But beyond its chameleon-like nature and the array of stunning colors it boasts, lies a fascinating structural complexity, especially when we start talking about its crystal cleavage. Those four-digit numbers you see associated with apatite’s cleavage planes? Yeah, they can be a real head-scratcher. So, let’s unravel this mystery together, shall we?

First things first: “Apatite” isn’t just one thing. Think of it more like a family of phosphate minerals i. The most common members of this family are fluorapatite, hydroxylapatite, and chlorapatite i. They’re all pretty similar, sharing the same basic crystal structure, but the key difference lies in which halogen ion – fluorine, hydroxyl, or chlorine – is calling the shots i. The general formula? Ca5(PO4)3(OH,F,Cl) .

Now, let’s talk cleavage. In the mineral world, cleavage refers to how a crystal breaks. It’s like finding the grain in a piece of wood; some minerals have a natural tendency to split along specific planes because the atomic bonds are weaker in those directions i. These planes are consistent for each mineral, which makes cleavage a super handy tool for identifying what you’re looking at i. We describe cleavage by how well it happens (perfect, good, etc.) and how it’s oriented within the crystal i.

Here’s where it gets interesting with apatite: it’s known to have poor cleavage i. What does that mean? Well, it can break along certain planes, but it’s not exactly easy or clean i. Think of trying to neatly tear a piece of paper that’s already crumpled – you might get a break, but it won’t be pretty. Apatite has two forms of imperfect cleavage: basal {0001} and prismatic {10-10} i.

Okay, deep breath. Time to tackle those four-digit codes: Miller indices. These are basically a secret language used by crystallographers to describe the orientation of a crystal plane i. Imagine them as coordinates that pinpoint exactly how a plane is positioned within the crystal’s framework i.

For hexagonal crystals, like our friend apatite, we use four numbers (hkil) i. The first three (h, k, i) relate to axes called a1, a2, and a3, which are all on the same plane and meet at 120-degree angles i. The fourth number (l) points to the c-axis, which stands straight up from that plane i.

To get these Miller indices, you look at where the crystal plane intersects the axes. If the plane runs parallel to an axis, its Miller index for that axis is zero i. A negative number gets a bar over it, like in (10-10) i.

So, let’s decode apatite:

  • (0001): This is basal cleavage, and remember, it’s poor in apatite i. This plane is like a flat surface perpendicular to the c-axis and parallel to the other three axes i. So, the crystal might cleave across the base of its hexagonal shape i.

  • (10-10): This is prismatic cleavage, also poor i. This plane runs parallel to the c-axis and cuts across the a1 axis i. The “-1” tells us it hits the a3 axis on the negative side and is parallel to the a2 axis i. This lines up with the faces of the hexagonal prism i.

“But wait,” you might ask, “why four digits for hexagonal crystals?” Good question! In these crystals, the first three axes are linked mathematically i. The index i is related to h and k by the equation i = -(h + k) i. You only need two numbers to really define the plane, but that third one (i) is included to keep things symmetrical and make it easier to see how different planes relate to each other i.

So, what’s the big deal about apatite’s cleavage? Well, its poor cleavage, combined with its middling hardness (5 on the Mohs scale), means it’s a bit fragile i. It scratches and chips relatively easily i. That’s why you don’t see apatite jewelry everywhere, though those transparent, colorful stones do get cut into gems i. It just takes a skilled hand and a lot of care i.

In conclusion, those seemingly random four-digit numbers are Miller indices, a sort of map reference for planes within the crystal i. Apatite might not cleave perfectly, but understanding these indices gives you a peek into its inner workings i. And that’s pretty cool, whether you’re a gemologist, a mineralogist, or just someone who appreciates the hidden beauty in the world around us i.

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